解决方法@H_403_10@

UIPrintInfo *pi = [UIPrintInfo printInfo];
pi.outputType = UIPrintInfoOutputGeneral;
pi.jobName = webView.request.URL.absoluteString;
pi.orientation = UIPrintInfoOrientationPortrait;
pi.duplex = UIPrintInfoDuplexLongEdge;

UIPrintInteractionController *pic = [UIPrintInteractionController sharedPrintController];
pic.printInfo = pi;
pic.showsPageRange = YES;
pic.printFormatter = webView.viewPrintFormatter;
[pic presentAnimated:YES completionHandler:^(UIPrintInteractionController *pic2,BOOL completed,NSError *error) {
    // indicate done or error
}];

Apple的开发网站上有一个更广泛的sample.